Kagome metals AV₃Sb₅

AV₃Sb₅ (A = K, Rb, Cs)

Also called CsV₃Sb₅, KV₃Sb₅, RbV₃Sb₅, kagome superconductors

van der Waals crystal superconductor

The kagome lattice – triangles meeting corner to corner – is the textbook setting for frustration, flat bands and topological band crossings, and this family puts one in a metal that superconducts. Below roughly 80–100 K the electrons freeze into a charge order with a 2×2 pattern that appears to pick a handedness and, by some measurements, to break time-reversal symmetry without any magnetic moments. Superconductivity follows at a few kelvin, and the two orders push against each other, which is why so much of the field is spent arguing about which one is doing what.

Key properties

  • A structurally perfect vanadium kagome net with Dirac points near the Fermi level; calculations classify all three compounds as Z2 topological metals
  • Charge order around 80–100 K with a 2×2 superlattice, seen as a gap at the Fermi level in tunnelling
  • Superconductivity at 2.5 K in CsV3Sb5 and ~0.9 K in KV3Sb5, with a gap-to-Tᴄ ratio near 5, a sign of strong coupling, and a pair density wave in CsV3Sb5
  • Muon spin relaxation reports internal fields appearing at the charge-ordering temperature – time-reversal symmetry breaking without local moments
  • A large anomalous Hall response accompanies the charge order, again with no magnetic order to explain it
  • The charge order also breaks rotational symmetry, giving electronic nematicity
  • In exfoliated thin flakes, selective oxidation dopes the layer: superconductivity rises and charge order is suppressed

How it is made

  • Single crystals from an alkali-metal-rich self flux, then decanted – the standard route for all three compounds
  • Mechanical exfoliation into thin flakes for device work, in an inert atmosphere
  • Deliberate surface oxidation of flakes as a doping knob, and potassium de-intercalation to shift the Fermi level

Uses, and how close they are

  • A model system for correlated and topological order on a kagome latticelab
  • Devices probing charge order and superconductivity in thin flakeslab

Readiness runs lab → prototype → pilot → deployed.

Open problems

  1. Does the charge order really break time-reversal symmetry? Muon and optical experiments disagree, and the answer decides whether this is a loop-current state
  2. Is the superconductivity conventional? Reports range from a nodeless multigap state to a pair density wave with strong coupling
  3. What sets the 2×2 (and 4a0) patterns: van Hove singularities at the Fermi level, phonons, or both?
  4. How far can the thin-flake route go – can a monolayer be isolated, and does either order survive it?

Going deeper

Short notes for specialists. Choose a lens in the header and yours comes first.

For theoreticians · your lens

The kagome band structure supplies Dirac points, van Hove singularities and flat bands in one lattice, and in AV3Sb5 the van Hove points sit close enough to the Fermi level for nesting to matter. Candidate charge orders include a chiral, possibly loop-current state that breaks time-reversal symmetry without spins, which would be a lattice realisation of long-discussed Haldane- and Varma-type models. The superconducting state is the second puzzle: pairing on top of a reconstructed Fermi surface, with pair density wave modulations reported in tunnelling. Calculations must treat the 2×2×2 (and larger) reconstructed cells, and the small energy differences between competing charge patterns make the answer sensitive to the functional and to phonons.

For experimentalists · your lens

Sample-to-sample variation is the field’s main confounder: alkali stoichiometry, residual flux and surface oxidation shift both transition temperatures. Report the charge-ordering and superconducting temperatures for each crystal, and the residual resistivity ratio. For time-reversal-symmetry claims, note that muon spin relaxation, Kerr and magneto-optical probes have not converged. In thin flakes, distinguish doping by oxidation from thickness effects by measuring both against a bulk reference.

For engineers · your lens

Not an engineering material: transition temperatures of a few kelvin and air-sensitive surfaces rule out devices. Its interest is scientific – a clean, exfoliable setting where charge order, topology and superconductivity meet – and as a test bed for measuring competing orders in thin flakes.

In the research tracks

Recent news

The newest items tagged CsV3Sb5, KV3Sb5, from the news feed updated 5 Oct 2026.

Preprintnot yet peer reviewed arXiv

Thickness-driven crossover from conventional to chiral nonreciprocal superconductivity in kagome metal CsV3Sb5

Superconductivity and its potential applications are governed by the symmetry of the superconducting order parameter. In the kagome metal CsV3Sb5, most bulk studies indicate conventional s-wave pairing. However, ultrathin flakes exhibit nonreciprocal transport, in particular a zero-field superconducting diode effect…

All 10 items tagged CsV₃Sb₅, KV₃Sb₅ in the news feed  ·  RSS feed for CsV₃Sb₅, KV₃Sb₅

Key references

  1. New kagome prototype materials: discovery of KV3Sb5, RbV3Sb5, and CsV3Sb5Ortiz et al. · Physical Review Materials 3, 094407 (2019)cited by 779doi:10.1103/PhysRevMaterials.3.094407
  2. CsV3Sb5: A Z2 topological kagome metal with a superconducting ground stateOrtiz et al. · Physical Review Letters 125, 247002 (2020)cited by 999doi:10.1103/PhysRevLett.125.247002
  3. Superconductivity in the Z2 kagome metal KV3Sb5Ortiz et al. · Physical Review Materials 5, 034801 (2021)cited by 481doi:10.1103/PhysRevMaterials.5.034801
  4. Unconventional chiral charge order in kagome superconductor KV3Sb5Jiang et al. · Nature Materials 20, 1353 (2021)cited by 742doi:10.1038/s41563-021-01034-y
  5. Concurrence of anomalous Hall effect and charge density wave in a superconducting topological kagome metalYu et al. · Physical Review B 104, L041103 (2021)cited by 414doi:10.1103/PhysRevB.104.L041103
  6. Roton pair density wave in a strong-coupling kagome superconductorChen et al. · Nature 599, 222 (2021)cited by 626doi:10.1038/s41586-021-03983-5
  7. Competition of superconductivity and charge density wave in selective oxidized CsV3Sb5 thin flakesSong et al. · Physical Review Letters 127, 237001 (2021)cited by 117doi:10.1103/PhysRevLett.127.237001
  8. Time-reversal symmetry-breaking charge order in a kagome superconductorMielke et al. · Nature 602, 245 (2022)cited by 501doi:10.1038/s41586-021-04327-z
  9. Charge-density-wave-driven electronic nematicity in a kagome superconductorNie et al. · Nature 604, 59 (2022)cited by 448doi:10.1038/s41586-022-04493-8