Niobium diselenide and disulfide

NbSe₂, NbS₂, NbTe₂

Also called NbSe₂, 2H-NbSe₂, NbS₂

van der Waals crystal superconductor

A metal that becomes a superconductor when cooled and stays one even as a single layer, which has made it the standard material for studying superconductivity in two dimensions. Because the spins of its electrons are locked by the crystal’s lack of inversion symmetry, a monolayer survives magnetic fields far beyond the usual limit for a superconductor. Its sulfur sibling 2H-NbS2 superconducts at a similar temperature but shows no charge density wave, so the pair separates the two effects.

Crystal structure

  • Nb
  • Se
Cell
Hexagonal, a = 3.44 Å
Atoms per cell
3
Nb–Se bond
2.60 Å
Height
3.35 Å between the outer atom centres
Trigonal prismatic like MoS2, but niobium has one d electron fewer than molybdenum, so the band that is full in MoS2 is half filled here and the layer is a metal. Bulk NbSe2 forms a 3×3 charge-density wave below about 33 K and superconducts below about 7 K, lower in a monolayer. The model shows the undistorted lattice. Geometry of bulk 2H-NbSe2: a = 3.44 Å, selenium planes 1.68 Å above and below the Nb plane.

Key properties

  • Superconducting transition at ~7.2 K in bulk, falling to ~3 K in the monolayer
  • Ising superconductivity: in-plane upper critical field in monolayers roughly six times the Pauli limit
  • Charge density wave (3×3) below ~33 K in bulk, strongly enhanced in the monolayer
  • Atomically flat superconducting electrode for van der Waals Josephson junctions
  • 2H-NbS2 superconducts at ~5.7–6 K with no charge density wave in bulk

How it is made

  • Vapour-transport growth of bulk crystals with iodine
  • Exfoliation and encapsulation inside a glovebox
  • MBE on bilayer graphene for spectroscopy
  • Salt-assisted CVD

Uses, and how close they are

  • Superconducting contacts and Josephson junctions in van der Waals stackslab
  • Superconducting diode and quantum-device researchlab

Readiness runs lab → prototype → pilot → deployed.

Open problems

  1. How do Ising superconductivity and the charge density wave compete or cooperate in the monolayer limit?
  2. Is pairing in few-layer NbSe2 purely conventional, or are triplet or nematic components present?
  3. Can NbSe2-based junctions host topological superconductivity when combined with magnets or topological insulators?
  4. Monolayer NbS2 has been reported to show a charge density wave that bulk crystals lack – what switches it on: reduced dimensionality, the substrate, or strain?

Going deeper

Short notes for specialists. Choose a lens in the header and yours comes first.

For theoreticians · your lens

The canonical Ising superconductor: broken inversion symmetry and spin–orbit coupling pin spins out of plane with opposite orientation in the two valleys. Electron–phonon calculations reproduce Tc only with careful treatment of anharmonicity and the charge density wave, which appears as soft phonon modes in harmonic DFT. NbS2 is the natural control: harmonic calculations predict a charge density wave there too, but anharmonic fluctuations of the lattice suppress it.

For experimentalists · your lens

Exfoliate and encapsulate in a glovebox. When measuring upper critical fields, align the field precisely in-plane – misalignment of a fraction of a degree dominates the result. STM images the 3×3 charge density wave directly, and Raman soft modes track its transition.

For engineers · your lens

Useful as a clean, atomically flat superconductor for research-grade quantum devices; air sensitivity and low transition temperature prevent broader use.

In the research tracks

Recent news

The newest items tagged NbSe2, NbS2, NbTe2, from the news feed updated 5 Oct 2026.

Preprintnot yet peer reviewed arXiv

Quantum Geometric Origin of Yu-Shiba-Rusinov States

In this work, we revisit the classic Yu-Shiba-Rusinov (YSR) problem of magnetic impurities in s-wave superconductors and uncover a quantum geometric origin of the YSR bound-state structure. The key geometric quantity is the momentum-space average of Bloch band projector over low-energy electrons, whose matrix rank…

Preprintnot yet peer reviewed arXiv

An All-van-der-Waals Qubit

Advances in solid-state physics, materials science, and device engineering have accelerated the development of superconducting qubits. Among emerging platforms, van der Waals (vdW) materials and their heterostructures are potentially attractive building blocks for quantum devices, yet their realization in qubit…

All 23 items tagged NbSe₂, NbS₂, NbTe₂ in the news feed  ·  RSS feed for NbSe₂, NbS₂, NbTe₂

Key references

  1. Two-dimensional atomic crystalsNovoselov et al. · PNAS 102, 10451 (2005)cited by 11,702doi:10.1073/pnas.0502848102
  2. Ising pairing in superconducting NbSe2 atomic layersXi et al. · Nature Physics 12, 139 (2016)cited by 1,231doi:10.1038/nphys3538
  3. Superconducting density of states and vortex cores of 2H-NbS2Guillamón et al. · Physical Review Letters 101, 166407 (2008)cited by 238doi:10.1103/PhysRevLett.101.166407