Iron germanium and gallium tellurides

FeₙGeTe₂ (n = 3, 4, 5), Fe₃GaTe₂

Also called Fe₃GeTe₂, Fe₅GeTe₂, Fe₃GaTe₂, FGT

van der Waals crystal magnet

A metallic magnet that can be thinned to a few atomic layers. Its bulk ordering temperature is far higher than that of the magnetic insulators, and with heavy electrical doping thin flakes have reached ferromagnetism at room temperature. Because it conducts, it can carry spin-polarised current directly – which is what spintronic memory needs. Its gallium sibling Fe3GaTe2 goes further: it stays ferromagnetic above room temperature without any doping, with its spins held firmly out of the plane.

Crystal structure

  • Te
  • Fe
  • Ge
Cell
Hexagonal, a = 3.94 Å
Atoms per cell
6
Fe–Te bonds
2.62 and 2.64 Å
Fe–Fe bonds
2.55 and 2.61 Å
Fe–Ge bonds
2.28 and 2.61 Å
Height
5.24 Å between the outer atom centres
A slab of iron and germanium sandwiched between two sheets of tellurium. In the middle plane, iron and germanium alternate around a honeycomb; above and below the centre of each hexagon sits an iron atom, and the two bond to each other straight through the plane. Real crystals are often missing some of the honeycomb iron, and fewer iron atoms mean a lower Curie temperature – about 220 K in nearly complete crystals, about 150 K in the iron-poor crystal this model was measured on. One layer of Fe3−xGeTe2 at 173 K (May and colleagues, Physical Review B 93, 014411, 2016): a = 3.94 Å. About 70% of the honeycomb iron sites were filled in the crystal measured; the model draws them all.

Key properties

  • Fe3GeTe2: bulk Curie temperature of roughly 200–230 K with strong out-of-plane anisotropy; around 130 K in the monolayer
  • Ionic-liquid gating raised the Curie temperature of thin flakes to room temperature (2018)
  • Fe5GeTe2 orders close to room temperature in bulk
  • Large anomalous Hall effect and magnetic skyrmions; used in all-van-der-Waals magnetic tunnel junctions
  • Fe3GaTe2: Curie temperature of ~350–380 K with large perpendicular magnetic anisotropy, and hard ferromagnetism reported down to the monolayer

How it is made

  • Vapour-transport or flux growth of bulk crystals
  • Mechanical exfoliation in a glovebox
  • MBE growth of wafer-scale films on GaAs, sapphire or topological insulators
  • Self-flux growth of Fe3GaTe2 crystals, and wafer-scale Fe3GaTe2 films

Uses, and how close they are

  • All-van-der-Waals magnetic tunnel junctions and spin–orbit torque deviceslab
  • Skyrmion-based memory conceptslab

Readiness runs lab → prototype → pilot → deployed.

Open problems

  1. Fe3GaTe2 orders above room temperature without gating – what lifts its Curie temperature so far above Fe3GeTe2’s, and can thin layers be made air-stable?
  2. What stabilises skyrmions and other chiral textures in a nominally centrosymmetric crystal – interfaces, defects or dipolar effects?
  3. Can wafer-scale MBE films match the magnetic quality of exfoliated flakes?

Going deeper

Short notes for specialists. Choose a lens in the header and yours comes first.

For theoreticians · your lens

An itinerant ferromagnet with inequivalent iron sites. DFT overestimates moments and Curie temperatures without careful treatment of correlations (DFT+DMFT has been applied), and heavy-fermion-like behaviour has been reported. Strong SOC-driven anisotropy stabilises 2D order; spin textures need micromagnetic models with Dzyaloshinskii–Moriya parameters taken from interfaces or defects.

For experimentalists · your lens

Anomalous Hall hysteresis is the quickest thickness-resolved magnetometry; Kerr microscopy and Lorentz TEM image domains and skyrmions. Iron deficiency lowers the Curie temperature, so check composition by EDS and report it.

For engineers · your lens

The most promising family for room-temperature 2D spintronics: Fe3GaTe2 is ferromagnetic above room temperature, and MBE offers a wafer-scale route. Air sensitivity and composition control are the immediate barriers.

In the research tracks

Recent news

The newest items tagged Fe3GeTe2, Fe3GaTe2, from the news feed updated 5 Oct 2026.

Preprintnot yet peer reviewed arXiv

Topological Hall Effect Induced by Chiral Spin Textures at the Ferroelectric/Ferromagnetic Interface

Chiral spin textures, largely driven by the Dzyaloshinskii-Moriya interaction, offer significant potential for next-generation computing technologies due to their chirality and topological stability. Ferroelectric/ferromagnetic van der Waals heterostructures are particularly appealing because they can combine…

Preprintnot yet peer reviewed arXiv

Magneto-optical Kerr spectroscopy of exciton Rydberg states in a magnetic van der Waals heterostructure

Excitonic states in two-dimensional semiconductors are sensitive to time-reversal symmetry breaking, yet how interfacial exchange acts on higher-lying exciton Rydberg states remains largely unexplored. Here we show that wavelength-resolved magneto-optical Kerr spectroscopy of a proximity-coupled MoSe2/Fe3GaTe2 van der…

Journal Physical Review B

Suppression of local magnetic moment formation and paramagnetic exchange interactions in monolayer Fe3GeTe2

We study the electronic and magnetic properties of monolayer Fe3GeTe2 within the density-functional plus dynamical mean-field theory approach in the paramagnetic phase. We argue that this compound is sufficiently far from the local magnetic moment limit, demonstrating n… [Phys. Rev. B 114, 165119] Published Mon Sep 14…

All 16 items tagged Fe₃GeTe₂, Fe₃GaTe₂ in the news feed  ·  RSS feed for Fe₃GeTe₂, Fe₃GaTe₂

Key references

  1. Fe3GeTe2 and Ni3GeTe2 – two new layered transition-metal compounds: crystal structures, HRTEM investigations, and magnetic and electrical propertiesDeiseroth et al. · European Journal of Inorganic Chemistry 2006, 1561 (2006)cited by 403doi:10.1002/ejic.200501020
  2. Gate-tunable room-temperature ferromagnetism in two-dimensional Fe3GeTe2Deng et al. · Nature 563, 94 (2018)cited by 2,639doi:10.1038/s41586-018-0626-9
  3. Two-dimensional itinerant ferromagnetism in atomically thin Fe3GeTe2Fei et al. · Nature Materials 17, 778 (2018)cited by 1,538doi:10.1038/s41563-018-0149-7
  4. Above-room-temperature strong intrinsic ferromagnetism in 2D van der Waals Fe3GaTe2 with large perpendicular magnetic anisotropyZhang et al. · Nature Communications 13, 5067 (2022)cited by 452doi:10.1038/s41467-022-32605-5