Iron selenide and iron telluride selenide

FeSe, FeTe₁₋ₓSeₓ

Also called FeSe, FeTe₁₋ₓSeₓ, FeTeSe, iron chalcogenide superconductors

van der Waals crystal superconductor

The structurally simplest iron-based superconductor, and the one that changes most when thinned. Bulk FeSe superconducts only below about 8 K, but a single layer grown on strontium titanate shows a superconducting gap that closes near 65 K – one of the most dramatic enhancements of superconductivity by an interface ever seen. Mixing in tellurium gives a crystal whose surface becomes a topological superconductor, one of the leading places to look for Majorana states.

Crystal structure

  • Fe
  • Se
Cell
Square, a = 3.77 Å
Atoms per cell
4
Fe–Se bond
2.38 Å
Height
2.92 Å between the outer atom centres
A square net of iron atoms, each inside a tetrahedron of four selenium atoms, two above the iron plane and two below. The height of the selenium above the iron plane, about 1.46 Å, is one of the structural parameters that track the superconducting transition temperature across the iron-based superconductors. Bulk tetragonal FeSe (anti-PbO type) at room temperature: a = 3.77 Å, selenium 1.46 Å above and below the Fe plane.

Key properties

  • Bulk FeSe: nematic (tetragonal-to-orthorhombic) transition at ~90 K without magnetic order, and superconductivity below ~8 K
  • Single-layer FeSe on SrTiO3: a superconducting gap that closes at ~65 K in photoemission, with higher onsets reported but disputed
  • FeTe is not a superconductor but a bicollinear antiferromagnet below ~60–70 K; substituting selenium brings superconductivity back
  • FeTe0.55Se0.45: its topological surface state becomes superconducting, and vortex cores show zero-energy bound states interpreted as Majorana modes
  • Pressure raises the transition temperature of bulk FeSe to roughly 37 K

How it is made

  • Bulk crystals by chemical vapour transport in an AlCl3/KCl flux, or by flux growth
  • Molecular beam epitaxy of single-layer FeSe on SrTiO3, followed by annealing
  • Mechanical exfoliation of FeSe and FeTe1−xSex flakes; molecular beam epitaxy of FeTe on topological insulators

Uses, and how close they are

  • A platform for Majorana bound states in topological quantum computing researchlab
  • Model system for superconductivity enhanced at interfaceslab

Readiness runs lab → prototype → pilot → deployed.

Open problems

  1. What lifts superconductivity in single-layer FeSe on SrTiO3: electron doping, coupling to substrate phonons, or both?
  2. How does nematic order form in FeSe without magnetism, and does it help or hinder pairing?
  3. Are the zero-energy vortex states in FeTe1−xSex Majorana modes, and why do only some vortices show them?

Going deeper

Short notes for specialists. Choose a lens in the header and yours comes first.

For theoreticians · your lens

FeSe challenges the usual picture of iron-based superconductors: nematicity without long-range magnetic order points to orbital or quantum-disordered spin physics, and strong correlations shrink its Fermi pockets far below DFT predictions. For monolayers on SrTiO3, electron doping from the substrate and forward-scattering coupling to substrate phonons are the leading explanations. In FeTe1−xSex, a band inversion along Γ–Z makes the surface topological.

For experimentalists · your lens

ARPES on monolayers grown in situ gives the gap-closing temperature; ex-situ transport needs capping and still differs between groups. For FeTe1−xSex, low-temperature STM with sub-meV resolution is needed to resolve vortex bound states, and inhomogeneity in the Te/Se ratio makes statistics over many vortices essential. Excess iron in FeTe changes its magnetism, so check the composition.

For engineers · your lens

Not an engineering material: its most interesting states appear only in single layers on particular substrates, in ultrahigh vacuum, or at a few kelvin. Its role is scientific, as a clean test of interface superconductivity and a candidate host for Majorana-based qubits.

In the research tracks

Recent news

The newest items tagged FeSe, FeTeSe, from the news feed updated 5 Oct 2026.

Preprintnot yet peer reviewed arXiv

A First-Principles Multiscale Framework for Topological Superconductivity

A microscopic understanding of topological superconductivity (TSC) in real materials requires a materials-informed approach that integrates first-principles electronic structure, superconductivity, and topology within a unified computational framework. Here, we develop such an approach by combining density functional…

Preprintnot yet peer reviewed arXiv

Controlling Intertwined Electronic Orders in FeSe with Exfoliation

Controlling intertwined electronic orders in two-dimensional superconductors offers an effective route to answering fundamental questions and engineering new quantum devices. However, tuning the balance between competing orders typically requires complex chemistry, strain, or interface engineering. Here, we show that a…

ExperimentFeSe, FeTeSe
Preprintnot yet peer reviewed arXiv

Altermagnetism-Induced Spin-resolved electronic structure in Janus FeX0.5Y0.5 Monolayers (X, Y = S, Se, Te)

Realizing the spin-resolved electronic properties in superconducting materials stands as a critical frontier, offering both novel fundamental physics and potential for dissipationless spin-based devices. Here, we predict a series of Janus FeX0.5Y0.5 monolayers derived from iron-based superconductors (e.g., FeSe, FeTe…

All 15 items tagged FeSe, FeTeSe in the news feed  ·  RSS feed for FeSe, FeTeSe

Key references

  1. Superconductivity in the PbO-type structure α-FeSeHsu et al. · PNAS 105, 14262 (2008)cited by 2,893doi:10.1073/pnas.0807325105
  2. Interface-induced high-temperature superconductivity in single unit-cell FeSe films on SrTiO3Wang et al. · Chinese Physics Letters 29, 037402 (2012)cited by 1,248doi:10.1088/0256-307X/29/3/037402
  3. Phase diagram and electronic indication of high-temperature superconductivity at 65 K in single-layer FeSe filmsHe et al. · Nature Materials 12, 605 (2013)cited by 823doi:10.1038/nmat3648
  4. Superconductivity above 100 K in single-layer FeSe films on doped SrTiO3Ge et al. · Nature Materials 14, 285 (2015)cited by 1,142doi:10.1038/nmat4153
  5. Observation of topological superconductivity on the surface of an iron-based superconductorZhang et al. · Science 360, 182 (2018)cited by 722doi:10.1126/science.aan4596
  6. Evidence for Majorana bound states in an iron-based superconductorWang et al. · Science 362, 333 (2018)cited by 754doi:10.1126/science.aao1797