Bismuth selenide and telluride

Bi₂Se₃, Bi₂Te₃, Sb₂Te₃

Also called Bi₂Se₃, Bi₂Te₃, Sb₂Te₃, tetradymite topological insulators

van der Waals crystal semiconductor

The best-known topological insulators: insulating inside, but with surfaces carrying electrons whose spin is locked to their direction of motion and which resist being scattered backwards. Bi2Te3 has also been the standard thermoelectric in solid-state coolers for decades. Thinning these crystals to a few layers lets the two surfaces interact, which changes their topology.

Crystal structure

  • Se
  • Bi
Cell
Hexagonal, a = 4.14 Å
Atoms per cell
5
Bi–Se bonds
2.85 and 3.07 Å
Height
6.97 Å between the outer atom centres
Five atomic planes, Se–Bi–Se–Bi–Se, make one quintuple layer, and quintuple layers stack with van der Waals gaps between them. Each bismuth atom sits in a distorted octahedron: three selenium atoms 2.85 Å away on the outer side, three 3.07 Å away towards the centre. The central selenium plane is an inversion centre. Bulk rhombohedral Bi2Se3 at room temperature: a = 4.14 Å.

Key properties

  • Single Dirac-cone surface state with spin–momentum locking, observed by ARPES in 2009
  • Surface-state gap opens below ~6 quintuple layers as top and bottom surfaces hybridise
  • Magnetically doped (Bi,Sb)2Te3 films showed the quantum anomalous Hall effect in 2013
  • Bi2Te3-based alloys are the commercial thermoelectrics in Peltier coolers near room temperature (ZT ~1)
  • Native selenium vacancies make Bi2Se3 n-type, so bulk conduction often masks surface transport

How it is made

  • Bridgman or melt growth of bulk crystals
  • MBE on Si(111), sapphire or graphene – the route to thin films for quantum anomalous Hall devices
  • Van der Waals epitaxy of nanoplates by CVD; mechanical exfoliation

Uses, and how close they are

  • Peltier coolers and thermoelectric generators (bulk Bi2Te3 alloys)deployed
  • Spin–orbit torque layers for magnetic memoryprototype
  • Quantum anomalous Hall devices and resistance standardslab

Readiness runs lab → prototype → pilot → deployed.

Open problems

  1. Can bulk carriers be eliminated so that topological surface transport dominates at room temperature?
  2. Can the quantum anomalous Hall effect be pushed well above a few kelvin for metrology or dissipationless interconnects?
  3. How robust is spin–orbit torque efficiency in industrially sputtered topological insulator films?

Going deeper

Short notes for specialists. Choose a lens in the header and yours comes first.

For theoreticians · your lens

The canonical three-dimensional strong topological insulators (Z2 = 1), with SOC-driven band inversion at Γ. DFT captures the topology but not always the gap size or the position of the Dirac point relative to the bulk valence band – GW matters for Bi2Te3. Thin films need slab models that include surface hybridisation and substrate-induced inversion asymmetry.

For experimentalists · your lens

Carrier density is the constant enemy: use antimony alloying, compensation doping or gating to bring the Fermi level into the bulk gap before claiming surface transport. ARPES confirms the Dirac cone; in Bi2Se3, Raman modes near 72, 131 and 174 cm−1 track thickness.

For engineers · your lens

Bi2Te3 is already a manufactured thermoelectric, though tellurium supply is limited and price-sensitive. For spintronics, sputtered topological insulator layers are being evaluated for spin–orbit torque MRAM, where integration temperature and interface quality are the issues.

In the research tracks

Recent news

The newest items tagged Bi2Se3, Bi2Te3, from the news feed updated 5 Oct 2026.

Preprintnot yet peer reviewed arXiv

Decoding Thermal Stability: In situ Insights into Phase Controlled Phosphine-free Colloidal Bi-Te Nanosheets

Bismuth telluride (Bi2Te3) is a prototypical V-VI semiconductor of interest for both thermoelectric and topological applications; however, phase-selective synthesis and thermal stability across the bismuth-telluride homologous series remain poorly understood. We report a facile and phosphine-free colloidal synthesis…

Preprintnot yet peer reviewed arXiv

Phonon-mediated closing of topological Floquet gaps in graphene: Non-phenomenological analysis

Floquet band engineering has been intensively studied for its potential to control material properties via laser driving. In particular, Floquet topological states have been measured on the surface of Bi2Se3. Nonetheless, the original prediction of Floquet topological bands in graphene remains unobserved, with works…

All 17 items tagged Bi₂Se₃, Bi₂Te₃ in the news feed  ·  RSS feed for Bi₂Se₃, Bi₂Te₃

Key references

  1. Topological insulators in Bi2Se3, Bi2Te3 and Sb2Te3 with a single Dirac cone on the surfaceZhang et al. · Nature Physics 5, 438 (2009)cited by 6,377doi:10.1038/nphys1270
  2. Crossover of the three-dimensional topological insulator Bi2Se3 to the two-dimensional limitZhang et al. · Nature Physics 6, 584 (2010)cited by 1,458doi:10.1038/nphys1689
  3. Experimental observation of the quantum anomalous Hall effect in a magnetic topological insulatorChang et al. · Science 340, 167 (2013)cited by 3,899doi:10.1126/science.1234414