Van der Waals heavy fermion CeSiI

CeSiI

Also called cerium silicide iodide

van der Waals crystal metal

Heavy-fermion physics, where localised f electrons hybridise with conduction electrons and make quasiparticles hundreds of times heavier than a free electron, used to require bulk intermetallic crystals. CeSiI brings it into the van der Waals world: it exfoliates, and the heavy-fermion behaviour survives into the ultrathin limit, so Kondo screening can now be gated, strained and stacked like any other 2D material.

Key properties

  • The first van der Waals crystal to show heavy-fermion behaviour down to ultrathin layers
  • Cerium moments are frustrated, and the material orders antiferromagnetically at low temperature
  • Kondo screening and magnetic order compete, which is the classic heavy-fermion setting – now in a layer that can be exfoliated
  • Nanoflake transport has been measured alongside the bulk, so the thickness dependence is being mapped directly
  • Strong spin–orbit coupling shapes the local moments, complicating the usual Kondo-lattice picture

How it is made

  • Bulk crystals by solid-state synthesis from the elements in sealed tubes
  • Mechanical exfoliation into flakes and nanoflakes for transport
  • Measurements under inert conditions, since the iodide surface is reactive

Uses, and how close they are

  • A tunable platform for Kondo lattice and heavy-fermion physics in two dimensionslab

Readiness runs lab → prototype → pilot → deployed.

Open problems

  1. How does Kondo screening change as the crystal is thinned, and is there a true monolayer limit for heavy-fermion behaviour?
  2. What is the interplay between frustrated magnetism and Kondo screening here?
  3. Can gating or strain drive the material across a quantum critical point, the way pressure does in bulk heavy fermions?
  4. Do heterostructures with other van der Waals layers change the Kondo temperature in a controlled way?

Going deeper

Short notes for specialists. Choose a lens in the header and yours comes first.

For theoreticians · your lens

A Kondo lattice in a layered geometry: f moments on cerium, conduction electrons in the same slab, and weak interlayer coupling that makes the problem genuinely two-dimensional. Strong spin–orbit coupling gives the local moments a multipolar character, so the effective pseudospins are not simple spin-1/2, and first-principles work has to supply Kondo-lattice parameters rather than assume them. The competition between magnetic exchange between f electrons and Kondo coupling to the conduction sea is the axis along which the phase diagram runs, and in 2D both are tunable by gating.

For experimentalists · your lens

Air sensitivity dominates the workflow: everything from exfoliation to contacts belongs in a glovebox, with encapsulation for transport. Compare bulk and nanoflake data on the same batch, because thickness and degradation both reduce the signature of heavy quasiparticles. Report the residual resistivity ratio and the temperature at which the resistivity turns over, since that is the marker of coherence.

For engineers · your lens

No device role. The point is scientific: it puts strongly correlated f-electron physics on the same experimental footing as graphene stacks, where gating and stacking are routine.

In the research tracks

Recent news

The newest items tagged CeSiI, from the news feed updated 5 Oct 2026.

Preprintnot yet peer reviewed arXiv

Structural responses incipient to pressure-driven antiferromagnetic quantum critical point of van der Waals heavy-fermion metal CeSiI

CeSiI is a van der Waals heavy-fermion metal recently found to exhibit unconventional superconductivity near a pressure-induced antiferromagnetic quantum critical point (QCP) at Pc =6 GPa. Here, we report a comprehensive single-crystal X-ray diffraction study of CeSiI under high pressures up to 8.3 GPa at room…

TheoryCeSiI
Preprintnot yet peer reviewed arXiv

Magnetic order, magnons, and crystal fields in van der Waals CeSiI

We report neutron, X-ray absorption, and resonant X-ray spectroscopy of magnetic excitations in the new heavy-fermion van-der-Waals superconductor CeSiI. We determined effective Hamiltonians and ground states of crystal electric fields and magnons. Isotropic Heisenberg interactions on a quasi two dimensional lattice…

TheoryCeSiI

All 3 items tagged CeSiI in the news feed  ·  RSS feed for CeSiI

Key references

  1. Magnetic frustration in a van der Waals metal CeSiIOkuma et al. · Physical Review Materials 5, L121401 (2021)doi:10.1103/PhysRevMaterials.5.L121401
  2. Two-dimensional heavy fermions in the van der Waals metal CeSiIPosey et al. · Nature 625, 483 (2024)cited by 43doi:10.1038/s41586-023-06868-x
  3. Nature of the unconventional heavy-fermion Kondo state in monolayer CeSiIFumega et al. · Nano Letters 24, 4272 (2024)cited by 13doi:10.1021/acs.nanolett.4c00619
  4. Glassy relaxation dynamics in the two-dimensional heavy fermion antiferromagnet CeSiITorres et al. · Nano Letters 25, 6848 (2025)cited by 3doi:10.1021/acs.nanolett.4c05920