Indium selenide and gallium selenide

InSe, GaSe, GaS, GaTe

Also called InSe, GaSe, GaS, GaTe, III–VI monochalcogenides

van der Waals crystal semiconductor

A semiconductor whose electrons are unusually light, so they move almost freely even in flakes a few layers thick. Few-layer InSe reached room-temperature mobilities around 1,000 cm2/(V·s) and showed the quantum Hall effect – among the best of any 2D semiconductor – and has since been used for ballistic transistors. It needs protection from air.

Crystal structure

  • Se
  • In
Cell
Hexagonal, a = 4.00 Å
Atoms per cell
4
In–In bond
2.79 Å
In–Se bond
2.65 Å
Height
5.39 Å between the outer atom centres
Four atomic planes, Se–In–In–Se. The two indium atoms bond to each other straight across the layer, and each also bonds to three selenium atoms in its own half. Electrons in InSe are light, about 0.14 me, which is why few-layer flakes reach high mobilities; the gap is 1.26 eV in bulk and widens as the flakes thin. One layer of bulk γ-InSe: a = 4.00 Å, In–In 2.79 Å, In–Se 2.65 Å.

Key properties

  • Room-temperature electron mobility ~1,000 cm2/(V·s) in hBN-encapsulated few-layer InSe; quantum Hall effect at low temperature
  • Light in-plane electron effective mass of ~0.14 m0
  • Strong thickness dependence of the band gap, from ~1.26 eV in bulk to above 2 eV in the monolayer
  • Monolayer valence band flattens into a ‘Mexican hat’, giving a van Hove singularity near the band edge
  • Ballistic InSe transistors with short gates reported in 2023

How it is made

  • Bridgman growth of bulk crystals
  • Mechanical exfoliation and encapsulation in an inert atmosphere
  • MBE, pulsed laser deposition and CVD thin films

Uses, and how close they are

  • High-mobility and ballistic transistorslab
  • Broadband photodetectorslab
  • Nonlinear optics and terahertz generation (bulk GaSe crystals)deployed

Readiness runs lab → prototype → pilot → deployed.

Open problems

  1. Can InSe be protected from degradation at wafer scale without losing its mobility?
  2. Can the ballistic transport of exfoliated flakes be reproduced in uniformly grown films?
  3. Does hole-doped monolayer InSe become magnetic, as its ‘Mexican hat’ valence band suggests?

Going deeper

Short notes for specialists. Choose a lens in the header and yours comes first.

For theoreticians · your lens

In the monolayer the valence band maximum moves off Γ into a ring, producing a van Hove singularity near the band edge; predictions of magnetism and enhanced thermoelectric response are therefore sensitive to spin–orbit coupling, strain and functional. The conduction band is s/p_z-like with a light mass, which is why phonon-limited mobility calculations predict high values.

For experimentalists · your lens

Exfoliate and encapsulate in an inert atmosphere. Confirm layer number via PL energy, which blue-shifts strongly with thinning, and Raman modes near 115, 177 and 227 cm−1. Bridgman crystals vary in stoichiometry, so check for indium-rich inclusions.

For engineers · your lens

A strong channel candidate on mobility grounds, but air sensitivity and the lack of wafer-scale growth hold it back; the 2023 ballistic transistors showed how far the channel can go.

In the research tracks

Recent news

The newest items tagged InSe, GaSe, from the news feed updated 5 Oct 2026.

All 17 items tagged InSe, GaSe in the news feed  ·  RSS feed for InSe, GaSe

Key references

  1. Tuning the bandgap of exfoliated InSe nanosheets by quantum confinementMudd et al. · Advanced Materials 25, 5714 (2013)cited by 639doi:10.1002/adma.201302616
  2. Electronic and optical properties of two-dimensional InSe from a DFT-parametrized tight-binding modelMagorrian et al. · Physical Review B 94, 245431 (2016)cited by 128doi:10.1103/PhysRevB.94.245431
  3. High electron mobility, quantum Hall effect and anomalous optical response in atomically thin InSeBandurin et al. · Nature Nanotechnology 12, 223 (2017)cited by 1,359doi:10.1038/nnano.2016.242
  4. Ballistic two-dimensional InSe transistorsJiang et al. · Nature 616, 470 (2023)cited by 439doi:10.1038/s41586-023-05819-w